基于液电效应的高压电脉冲对煤体致裂实验研究*

为分析基于液电效应的高压电脉冲致裂煤体效果，采用电脉冲应力波实验和微观观测方法对潞安矿区煤样裂隙发展过程及其特征进行研究。结果表明:液电效应能明显致裂煤体，且作用次数越多，煤体裂隙密度越大、裂隙网络越贯通，同时煤体孔裂隙等结构薄弱部位的存在能促进裂隙的发育；液电效应对煤体作用可分为4个阶段，其中裂隙快速发展阶段是适合现场作用阶段；高压电脉冲通过液电效应产生冲击波和其他次生作用，且对煤体组成成分无影响；在现场应用中，应充分考虑煤体性质、钻孔布局等，采用“单点多次、多次连续、分段进行、全孔作业”的作业方式。该实验研究为基于液电效应的高压电脉冲技术应用提供支撑。     

Synergistic suppression effects of flame retardant,porous minerals and nitrogen on premixed methane/air explosion

A novel composite inhibitor based on porous mineral materials and conventional flame retardant of ammonium polyphosphate (APP) is prepared to suppress the premixed methane/air explosion. Taking advantages of gas and powder inhibitor, N₂ and the prepared composite inhibitor are combined to use. The suppression performance of N₂-composite inhibitor on methane explosion is investigated on a 20-L spherical experimental explosion apparatus and the characteristic pressure data are obtained. The combined inhibition effects of N₂ and the prepared composite inhibitor are greater than either acting alone. Thermal decomposition behavior and gaseous products of composite inhibitor are analyzed with thermogravimetric analysis and thermogravimetric-mass spectrometry, respectively. Based on physical and chemical actions, the inhibition mechanisms of N₂-composite inhibitor system are proposed. This work provides a reference to prepare high-performance gas explosion inhibitor based on the synergism of binary or multiple components.     

近断层地震作用下考虑温度和碰撞效应的曲线梁桥地震响应分析

为探究大温差地区曲线梁桥在近断层脉冲型地震动作用下的地震响应和碰撞效应，以西北大温差地区某曲线连续梁桥为工程实例，建立全桥非线性有限元模型并考虑变温作用对支座刚度的影响；分别以桥墩内力、支座位移和邻梁碰撞效应为指标研究曲线梁桥在近断层脉冲型地震动作用下的地震反应特性。结果表明:温度越低，地震波作用于结构的内力响应越大；曲线梁桥在地震动作用下邻梁间碰撞为面-面碰撞，且温度越高，碰撞效应越强；高阻尼橡胶支座在低温下体现出较强的耗能能力，在大温差地区的桥梁抗震设计中可作为参考；近断层脉冲地震动相较于远场地震动，结构地震响应更大，对结构的破环性更强，故在近断层地区的桥梁抗震设计中应予以重视。     

Identifying important species that amplify or mitigate the interactive effects of human impacts on marine food webs

Some species may have a larger role than others in the transfer of complex effects of multiple human stressors, such as changes in biomass, through marine food webs. We devised a novel approach to identify such species. We constructed annual interaction-effect networks (IENs) of the simulated changes in biomass between species of the southeastern Australian marine system. Each annual IEN was composed of the species linked by either an additive (sum of the individual stressor response), synergistic (lower biomass compared with additive effects), or antagonistic (greater biomass compared with additive effects) response to the interaction effect of ocean warming, ocean acidification, and fisheries. Structurally, over the simulation period, the number of species and links in the synergistic IENs increased and the network structure became more stable. The stability of the antagonistic IENs decreased and became more vulnerable to the loss of species. In contrast, there was no change in the structural attributes of species linked by an additive response. Using indices common in food-web and network theory, we identified the species in each IEN for which a change in biomass from stressor effects would disproportionately affect the biomass of other species via direct and indirect local, intermediate, and global predator–prey feeding interactions. Knowing the species that transfer the most synergistic or antagonistic responses in a food-web may inform conservation under increasing multiple-stressor impacts.     

微乳液增敏罗丹明B氧化褪色光度法测定微量亚硝酸根

基于微乳液对亚硝酸根催化溴酸钾氧化罗丹明B褪色反应具有增敏作用的原理，建立了催化动力学光度法测定痕量亚硝酸根的新方法。实验结果表明：该方法的最佳反应条件为1×10^-4 mol/L的罗丹明B溶液加入量0.60 mL，1 mol/L的稀磷酸加入量1.50 mL，0.1 mol/mL的溴酸钾溶液0.50 mL，反应温度20 ℃，反应时间15 min;对亚硝酸根测定的线性范围为ρ（NO₂^-）= 0.048~0.800 μg/mL，检出限为0.003 0 μg/mL;加入微乳液后催化反应的灵敏度增大了3倍。     

Evaluation of the impact of matrix effects in LC/MS measurement on the accurate quantification of neonicotinoid pesticides in food by isotope-dilution mass spectrometry

The use of isotope-labeled internal standards is the most widely accepted approach to overcome the matrix effects on quantification of pesticides in food by LC/MS. We evaluated the impact of the matrix effects on quantification of six neonicotinoid pesticides, acetamiprid, clothianidin, dinotefuran, imidacloprid, thiacloprid, and thiamethoxam, in food by using deuterated internal standards. The calibration curves for each pesticide were obtained by using matrix-free and matrix-matched calibration solutions with blank brown rice, carrot, and green onion extracts. For brown rice and carrot, the matrix effects were not observed. In contrast, the slopes of calibration curves for each pesticide were influenced by presence of green onion extracts in calibration solutions (variability of the slopes was 4–9%), because the ratios of peak area for native pesticide to those for internal standards were influenced by matrix. The spike-and-recovery test with green onion was also performed. The analytical values obtained by using matrix-free calibration solution were biased from the spiked concentration, whereas those obtained by using matrix-matched calibration solution were comparable to the spiked concentration. These results indicate that matrix-matched calibration solution should be used for accurate quantification of neonicotinoid pesticides in food by LC/MS using deuterated internal standards.     

农田土壤碳循环过程及其量化方法

已有研究表明除了作物碳（根际沉积碳和秸秆碳）对农田土壤有机碳（SOC）的输入外，土壤碳还来源于土壤自养微生物固定SOC的贡献以及土壤无机碳（SIC）的固定（无机化学途径和微生物的生物矿化途径）.农田SOC的高低主要受到外源作物碳输入和原有SOC分解的平衡作用.作物碳输入在短期内通常促进SOC的分解，呈现正（根际）激发效应.通过整合分析主要作物的根际激发效应和秸秆还田的激发效应的研究，发现作物根系生长和秸秆还田引起的（根际）激发效应大小平均值分别为75%和67%.尽管秸秆还田通过激发效应引起SOC分解的额外释放，但是土壤残留秸秆碳通常大于激发效应导致SOC的额外损失，因此秸秆还田可能增加SOC的储量.在农田系统中，秸秆碳和根际沉积碳往往共存，这导致土壤碳输入和输出至少有3个碳源（根际沉积碳、秸秆碳和土壤碳），由于多碳源体系的区分方法存在挑战，目前这两种作物碳（根际沉积碳和秸秆碳）对SOC分解的激发效应影响是不清晰的.最后，提出了新量化方法，可以多源区分根际CO₂排放以及SOC中作物碳输入的碳源，以及区分碱性土壤中无机化学和微生物途径对SIC的贡献.研究有助于提高对农田土壤SOC和SIC输入和输出途径的理解，以及农田土壤碳平衡评估的精确度.     

云母类矿物钾肥的施用效应

我国钾资源贫乏，目前使用的钾肥主要靠国外进口．通过物理、化学和生物的方法，对云母类矿石进行活化而制成云母类矿物钾肥，不失为解决我国南方土壤钾素缺乏问题的一条有效途径．本文对中科院地化所提供的通过活化处理制取的云母类矿物钾肥进行了肥效试验．结果表明，施用云母类矿物钾肥与施用等钾量的氯化钾相比，无论是作物的吸钾能力，还是土壤的供钾能力．前者都比后者显著提高．因此，开发云母类矿物钾肥资源具有广阔的前景．     

基于城镇化的居民生活能源消费碳排放门限效应分析

正确认识城镇化发展中碳减排的阶段性特征和应对我国城镇化进程中的碳排放挑战,具有重要的理论参考价值和现实指导意义。现有研究较少关注城镇化发展对居民生活能源消费碳排放的影响,未能将城镇化自身阶段性变化对生活碳排放的影响联系起来。基于此,本文以城镇化率作为门限变量,以生活能源结构、居民消费率、产业结构分别作为解释变量,构建多个不同视角的门限-STIRPAT扩展模型,深入分析城镇化水平处于不同阶段时,居民生活能源消费碳排放所受影响的差异性。研究表明,城市化率分别处于门限值(0.250、0.325和0.457)前后时,居民生活能源消费碳排放所受影响出现了阶段性的变化。当城镇化率低于0.250时,能源结构、居民消费率和产业结构对居民生活能源消费碳排放均呈负向弹性关系,分别为-0.688、-0.570、-0.570;当城市化率低于0.457时,能源结构、居民消费率和产业结构对居民生活能源消费碳排放的负向弹性关系仍然存在,但相关关系明显减弱,能源结构负向弹性关系介于(-0.338,-0.019),居民消费率和产业结构负向弹性关系为-0.251。当城市化率超过0.457时,能源结构、居民消费率和产业结构对居民生活能源消费碳排放已逐步显现或转变为正向弹性关系。基于上述研究结果提出相应建议:区域城镇化发展介于(0.250,0.457]这一阶段的进程中,应把握住能源结构、居民消费率和产业结构对居民生活能源消费碳排放影响效应转变之前的阶段,鼓励居民生活消费,但进行节能低碳生活方式的引导,大力发展第三产业,满足居民对生活商品及服务的需求。当区域城镇化提升至0.457以上时,应合理优化能源结构,提高非化石能源比重,通过财政政策等对居民生活消费进行调控和引导,注重第三产业中的科技、金融等技术密集型的行业发展。     

The influences of recycle effect on double-pass V-corrugated solar air heaters

The study of the heat transfer enhancement for the recycling double-pass V-corrugated solar air heaters, which implement the external recycle of flowing air, was investigated experimentally and theoretically. The comparison among different designs of V-corrugated, baffled and fins attached, and flat-plate collectors was made to show the device performance improvement with various operating parameters under the same working dimensions. The recycling double-pass V-corrugated device developed here was proposed in aiming to strengthen the convective heat-transfer coefficient and enlarge the heat transfer area. The error analysis of experimental results deviate by 0.85–2.46% from the theoretical predictions with the fairly good agreement, and both results show that the device performance of the recycling double-pass V-corrugated operation is better than those of the other configurations under various recycle ratios and mass flow rates. The suitable selections were obtained for operating recycling double-pass V-corrugated devices while considering with an economic viewpoint by both the collector efficiency enhancement and the power consumption increment.